1Temperature Curie_Presentation (1)
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1Temperature Curie_Presentation (1)

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08.05.2020
1Temperature Curie_Presentation (1)
1Temperature Curie_Presentation (1).pdf

 

Curie Temperature

Neil McGlohon & Nathan Beck (2012)

Tim Corbly & Richard Mihelic (2013)

The Curie Point

      Curie point, also called Curie Temperature,  temperature at which certain magnetic materials undergo a sharp change in their magnetic properties.

      This temperature is named for the French physicist Pierre Curie, who in 1895 discovered the laws that relate some magnetic properties to change in temperature.

      At low temperatures, magnetic dipoles are aligned. Above the curie point, random thermal motions nudge dipoles out of alignment.

An example of a curie pendulum which utilizes the effects of heat on a ferromagnetic substance’s magnetization. The motion is periodic and follows the heating/cooling process of the swinging bob.

Curie Pendulum

      The heat engine uses a principle of magnetism discovered by Curie. He studied the effects of temperature on magnetism.

      Ferromagnetism covers the field of normal magnetism that people typically associate with magnets. All normal magnets and the material that are attracted to magnets are ferromagnetic materials.

      Pierre Curie discovered that ferromagnetic materials have a critical temperature at which the material loses their ferromagnetic behavior. This is known as its Curie Point.

      Once the material reaches the Curie Point, it will lose some of its magnetic properties until it cools away from the heat source and regains its magnetic properties. It is then pulled into the heat source again by the engine magnet to cycle through again.

The heat source could be a flame or even a light depending on the material of the bob.

Heat Engines

      A heat engine transfers energy from a hot reservoir to a cold reservoir, converting some of it into mechanical work.

      No engine operating between two heat reservoirs can be more efficient than a Carnot engine operating between the same reservoirs.

      Examples of heat engines:

      Curie point

      Stirling Engine Steam engine

      Elastic engine

Diagram of Apparatus

How it works!

H: magnetic field intensity

M: magnetization

How it works!

Carnot Cycle PV Diagram

Our heat engine is not exactly a Carnot cycle, however there are similarities between it and our HM diagram.

Paramagnetism vs. Ferromagnetism

   Materials are made up of magnetic domains, which contain atomic dipoles coupled together in some direction.

   Typically, these domains are aligned in random directions, and so there is no overall magnetic direction.

   In the presence of a magnetic field, domains parallel to the field grow while others shrink.

   Paramagnetic materials have a positive magnetic susceptibility. Ferromagnetic materials have a strong positive susceptibility.

   Ferromagnetic materials can remain magnetized after the external field is removed.

The Curie Point

Gadolinium has a Curie Temperature of 293 K.

This is equivalent to around 20 degrees Celsius. This makes for a good material in a light based Curie Pendulum.

Data from F. Keffer, Handbuch der Physik, 18, pt. 2, New York: SpringerVerlag, 1966 and P. Heller, Rep. Progr. Phys., 30, (pt II), 731 (1967)

Temperatures of Interest

    Nickel has a Curie Temperature of 627K.

    We expect the bob to follow an oscillatory path that orbits the curie point with a period under 10 seconds (from observation of examples).

Candle Temperature Profile

Horizontal distance from flame:

Source: http://www.sciencedirect.com/science/article/pii/S0143816699000378

Neodymium Magnets

Could we damage the magnet itself with the flame?

We could, if the magnet crosses its Curie point, it will permanently lose its magnetization. But from the flame profile in the previous slide the magnet is kept at a safe enough horizontal distance to avoid damage. The magnet stayed cool enough to touch throughout the experiment.

Example of Basic Apparatus

Mark I

Period of about 7 seconds.

Mark II

Period of about 5 seconds.

Stefan-Boltzmann Law - Cooling

Energy radiated by a blackbody radiator per second per unit area is proportional to the fourth power of the absolute temperature and is given by the Stefan‐Boltzemann Law:

                                                                                                                                                      P         4

T A

But not every radiator is ideal – in which case the proportionality constant for emissivity is

introduced:                            P           4

(ideal radiator: e = 1)            eT

A

Stefan-Boltzmann Law - Cooling

    If the hot object is radiating energy to its cooler surroundings at temperature Ts then the total energy radiated is:

PeA(T4 Ts4)

    Our concern with this is the candle soot that builds up on the pendulum bob could affect the emissivity of the nickel and change the properties of the system over time.

Data - Magnetic Field

Measurements with a magnetic field probe, output a voltage corresponding to two different sweet spots that measured the Axial and Transverse potential at a given point.

X                 distance: Horizontal distance from edge of magnet. Positive away.

Y                 distance: vertical distance from center of magnet. Positive down.

State 1, the position of the bob when it is at its maximum magnetic field amplitude.

State 2, the position of the bob after it falls from the magnet.

Missing Data - Temperature

    Optimally we would have spot welded a thermocouple to the bob to measure its temperature at the different spots. This would allow us to have a definitive number for the amount of work we have harvested from the candle.

Possible issues:

    The thermocouple is not without mass, this could affect how the bob interacts with the magnet, change the period, etc.

    The Thermocouple may be ferromagnetic itself and have a different curie point than that of the bob, this could alter how the magnet interacts with the bob as well.

Thoughts – How can we benefit?

    Hopes:

    To make a more efficient heat engine.

    Optimally we would have a ferromagnetic pendulum bob with a non‐ferromagnetic, non‐conducting swing rod.

    Use a Ratchet system to take energy out

    Concerns:

    The soot from the candle can effect the cooling and heating rate of the bob.

    The candle flame is not stable

    The current pendulum rod is both conducting and ferromagnetic.

    Due to the geometry of the bob, there are two nodes that it can stably reside in. For the most part during operation, it prefers the lower of the two, which is optimal.

Possible Improvements

Mark III – Rotary Curie Engine

Examples of Rotary Type

Aluminum disk with a continuous nickel loop

Aluminum disk with individual nickel loops

Example of Rotary Curie Engine

The period of this engine was approximately 1 rotation every 5 seconds at an average of 16°C outside temperature. The temperature between the disk and light fluctuated between 65°C and 85°C and the temperature next to the light was about 90°C.

Sources:

      http://scitoys.com/scitoys/scitoys/magnets/magnets.html#curie_effect

      http://dx.doi.org/10.1119/1.14959

      http://www.imagesco.com/articles/heatengine/HeatEngine.html

      http://www.sciencedirect.com/science/article/pii/S0143816699000378

      http://www.youtube.com/watch?feature=endscreen&v=RWrTvBoK94&NR=1

      http://fire.nist.gov/bfrlpubs/fire05/PDF/f05141.pdf

      http://www.omega.com/literature/transactions/volume1/emissivityb.html

      http://hyperphysics.phy‐astr.gsu.edu/hbase/thermo/stefan.html

      http://chemwiki.ucdavis.edu/@api/deki/files/7647/=Screen_shot_201012‐16_at_12.39.24_PM.png

      http://library.thinkquest.org/C006011/english/sites/thermo3.php3?v=2 http://www.doitpoms.ac.uk/tlplib/ferromagnetic/curie‐weiss.php

      http://www.sciencedirect.com/science/article/pii/S0304885308011487

Curie Temperature

Curie Temperature

Neil McGlohon & Nathan Beck (2012)

Neil McGlohon & Nathan Beck (2012)

The Curie Point • Curie point, also called

The Curie Point • Curie point, also called

Ferromagnetism covers the field of normal magnetism that people typically associate with magnets

Ferromagnetism covers the field of normal magnetism that people typically associate with magnets

No engine operating between two heat reservoirs can be more efficient than a

No engine operating between two heat reservoirs can be more efficient than a

Diagram of Apparatus How it works!

Diagram of Apparatus How it works!

H: magnetic field intensity

H: magnetic field intensity

1Temperature Curie_Presentation (1)

1Temperature Curie_Presentation (1)

Carnot Cycle PV Diagram Our heat engine is not exactly a

Carnot Cycle PV Diagram Our heat engine is not exactly a

Paramagnetism vs. Ferromagnetism

Paramagnetism vs. Ferromagnetism

Materials are made up of magnetic domains, which contain atomic dipoles coupled together in some direction

Materials are made up of magnetic domains, which contain atomic dipoles coupled together in some direction

The Curie Point Gadolinium has a

The Curie Point Gadolinium has a

Data from F. Keffer, Handbuch der

Data from F. Keffer, Handbuch der

Candle Temperature Profile

Candle Temperature Profile

We could, if the magnet crosses its

We could, if the magnet crosses its

Example of Basic Apparatus

Example of Basic Apparatus

Mark I Period of about 7 seconds

Mark I Period of about 7 seconds

Mark II Period of about 5 seconds

Mark II Period of about 5 seconds

Stefan-Boltzmann Law - Cooling •

Stefan-Boltzmann Law - Cooling •

T A Stefan-Boltzmann Law -

T A Stefan-Boltzmann Law -

• of the nickel and change the properties of the system over time.

• of the nickel and change the properties of the system over time.

Data - Magnetic Field Measurements with a magnetic field probe, output a voltage corresponding to two different sweet spots that measured the

Data - Magnetic Field Measurements with a magnetic field probe, output a voltage corresponding to two different sweet spots that measured the

Missing Data - Temperature •

Missing Data - Temperature •

Thoughts – How can we benefit? •

Thoughts – How can we benefit? •

Possible Improvements • Mark

Possible Improvements • Mark

Examples of Rotary Type Aluminum disk with a continuous nickel loop

Examples of Rotary Type Aluminum disk with a continuous nickel loop

Example of Rotary Curie Engine

Example of Rotary Curie Engine

Sources: • http://scitoys

Sources: • http://scitoys
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