5Electromotive force and internal resistance of current source.

Electromotive Force: Terminal Voltage

When you forget to turn off your car lights, they slowly dim as the battery runs down. Why don’t they simply blink off when the battery’s energy is gone? Their gradual dimming implies that battery output voltage decreases as the battery is depleted.

Furthermore, if you connect an excessive number of 12-V lights in parallel to a car battery, they will be dim even when the battery is fresh and even if the wires to the lights have very low resistance. This implies that the battery’s output voltage is reduced by the overload.

The reason for the decrease in output voltage for depleted or overloaded batteries is that all voltage sources have two fundamental parts—a source of electrical energy and an internal resistance. Let us examine both.

Electromotive Force

You can think of many different types of voltage sources. Batteries themselves come in many varieties. There are many types of mechanical/electrical generators, driven by many different energy sources, ranging from nuclear to wind. Solar cells create voltages directly from light, while thermoelectric devices create voltage from temperature differences.

All such devices create a potential difference and can supply current if connected to a resistance. On the small scale, the potential difference creates an electric field that exerts force on charges, causing current. We thus use the name electromotive force, abbreviated emf.

Emf is not a force at all; it is a special type of potential difference. To be precise, the electromotive force (emf) is the potential difference of a source when no current is flowing. Units of emf are volts.

A variety of voltage sources (clockwise from top left): the Brazos Wind Farm in Fluvanna, Texas (credit: Leaflet, Wikimedia Commons); the Krasnoyarsk Dam in Russia (credit: Alex Polezhaev); a solar farm (credit: U.S. Department of Energy); and a group of nickel metal hydride batteries (credit: Tiaa Monto). The voltage output of each depends on its construction and load, and equals emf only if there is no load.

Electromotive force is directly related to the source of potential difference, such as the particular combination of chemicals in a battery. However, emf differs from the voltage output of the device when current flows. The voltage across the terminals of a battery, for example, is less than the emf when the battery supplies current, and it declines further as the battery is depleted or loaded down. However, if the device’s output voltage can be measured without drawing current, then output voltage will equal emf (even for a very depleted battery).

Internal Resistance

As noted before, a 12-V truck battery is physically larger, contains more charge and energy, and can deliver a larger current than a 12-V motorcycle battery. Both are lead-acid batteries with identical emf, but, because of its size, the truck battery has a smaller internal resistance r. Internal resistance is the inherent resistance to the flow of current within the source itself.

[link] is a schematic representation of the two fundamental parts of any voltage source. The emf (represented by a script E in the figure) and internal resistance r are in series. The smaller the internal resistance for a given emf, the more current and the more power the source can supply.

Any voltage source (in this case, a carbon-zinc dry cell) has an emf related to its source of potential difference, and an internal resistance r related to its construction. (Note that the script E stands for emf.). Also shown are the output terminals across which the terminal voltage  V is measured. Since V=emf-Ir, terminal voltage equals emf only if there is no current flowing.

The internal resistance r can behave in complex ways. As noted, r increases as a battery is depleted. But internal resistance may also depend on the magnitude and direction of the current through a voltage source, its temperature, and even its history. The internal resistance of rechargeable nickel-cadmium cells, for example, depends on how many times and how deeply they have been depleted.

Why are the chemicals able to produce a unique potential difference? Quantum mechanical descriptions of molecules, which take into account the types of atoms and numbers of electrons in them, are able to predict the energy states they can have and the energies of reactions between them.

In the case of a lead-acid battery, an energy of 2 eV is given to each electron sent to the anode. Voltage is defined as the electrical potential energy divided by charge: V=\frac{{P}_{\text{E}}}{q}. An electron volt is the energy given to a single electron by a voltage of 1 V. So the voltage here is 2 V, since 2 eV is given to each electron. It is the energy produced in each molecular reaction that produces the voltage. A different reaction produces a different energy and, hence, a different voltage.

Terminal Voltage

The voltage output of a device is measured across its terminals and, thus, is called its terminal voltage. Terminal voltage is given by

V=emf-Ir

where r is the internal resistance and I is the current flowing at the time of the measurement.

I is positive if current flows away from the positive terminal, as shown in [link]. You can see that the larger the current, the smaller the terminal voltage. And it is likewise true that the larger the internal resistance, the smaller the terminal voltage.

Suppose a load resistance R  is connected to a voltage source. Since the resistances are in series, the total resistance in the circuit is R+r.